Saturday, October 12, 2019
International business Essay -- essays research papers fc
Protectionism in the global economy The global economy has seen a dramatic increase in services trade between countries. The regulation and monitoring of service trade between countries has become much harder. As highlighted by Johnson, trading in services was the fastest growing constituent of global trade during the 80ââ¬â¢s and 90ââ¬â¢s. Cross border transactions include anything from banking to software. When services are offered to another country, the provider has to interact with the customer through either, cross border communications, movement of the provider or the consumer moving to the supplierââ¬â¢s state of residence. Technology has made international trade much easier and more feasible; this has lead countries to boost services being exported to other countries. IT has decreased the cost of communication between countries. As a result it has made it more feasible for businesses to introduce new products and modify services abroad. This spark in global trade of services has its downfalls. The lib eralization of services goes against certain countriesââ¬â¢ development strategies. Areas like health and education needs the provisional planning of governments. The interference from abroad has hindered the governmentsââ¬â¢ strategic planning with respect to these services. This takes us to the importance of regulating services coming in from abroad through protectionism. Regulations on services can be a burden on service providers which can consequently weaken the liberalization of tr...
Friday, October 11, 2019
Analysis of Twain’s on the Decay of the Art of Lying
Critical Analysis On the Decay of the Art of Lying by Mark Twain ââ¬Å"Lying is universal ââ¬â we all do it. â⬠In the essay, the author believes that all men lie because we must lie. There are many instances wherein men were prompted to lie at some point of their lives for the benefit of others. According to him, itââ¬â¢s better to give a good lie than a destructive truth. Lying for otherââ¬â¢s advantage was given precedence than telling the truth at all times no matter how it hurts. Unfortunately, lying is easily covered with different alibis and given little thought of how destructive it might become on the long run. Twain considers lying as a noble art. It is the fourth grace and an eternal virtue. ââ¬Å"Judicious lying is what the world needs,â⬠he said. Heââ¬â¢d sometimes think that itââ¬â¢s better not to lie if the lie will be destructive to others. For him, a habitual truth-teller [someone who speaks truthfully at all times] doesnââ¬â¢t exist and had never existed. The author gives us a simple look on how lying had become the fad of his generation. Even in the tiniest of things, people tend to lie. It goes to show that many are pretentious and still is today. However, the author overlooks one thing. True ââ¬â a lie for the good of another might be reasonable ââ¬â but lying will always be lying. Truth hurts indeed but a lie hurts even more when unveiled. As far as God is concerned, liars go to hell. A small lie can lead people to the lake of fire. Of course, God forgives sins. He forgives lying, too, so long as the person will repent from it. Avoiding lies might be hard to do with all the deception and temptation going on around but itââ¬â¢s not impossible. Fearing to tell the truth means that youââ¬â¢re afraid of what will happen to you. In order to protect oneââ¬â¢s self from being punished or from hurting others, lying becomes the scapegoat. Eventually, it develops into a habit and you become a ââ¬Ëmasterââ¬â¢ at it. For Twain, he is still a newbie in this game. He would like for this art to be cultivated in the forms of charitable and unselfish lying. Again, lying is always and has always been a manifestation of selfishness. Lastly, uttering lies wonââ¬â¢t disappear in the years ahead but itââ¬â¢s elevation as a virtue might need some thinking. It is an agonizing fact that some think the same way as Twain does. The difference is that he (Twain) was able to voice out his opinions in a very artistic way through his writing while other people donââ¬â¢t care that much. This essay is an eye opener for all the people in this world about the art of lying. This form of art encompasses race, gender and culture. Different punishments await the liar but that never abolished it altogether. As long as people continue to let lies surround them, this art wonââ¬â¢t be decaying soon. ââ¬Å"For the sin of their mouth and the words of their lips let them even be taken in their pride: and for cursing and lying which they speak. â⬠Psalm 59:12 KJV
Thursday, October 10, 2019
Quantitative Determination of Total Hardness In Drinking Water Essay
Abstract This experiment is about the determination of water hardness through the use of complexometric EDTA titration. Determination of water hardness is important to find out the most suitable water hardness under particular circumstances. This was conducted for the purpose of applying the concept of complexometric titration using an efficient chelating agent, EDTA. Sample mineral water was analyzed using standard EDTA with EBT as indicator, and calcium ions present in the solution were calculated to determine the hardness of the water sample. At the end of the experiment, the results indicated that the mineral sample water has large amounts of calcium and magnesium ionsââ¬âan implication of a hard water sample. INTRODUCTION Water hardness is a measure of the amount of calcium and magnesium present in sample water. These calcium and magnesium ions have the capacity to replace sodium or potassium ions and form sparingly soluble products or precipitates. Water hardness is involved in various aspects of industrial and biochemical processes. Large amounts of ppm CaCO3 in water can form precipitates when interacted with soap and form rings known as ââ¬Å"scumâ⬠in several utensils and appliances. The formation of these ââ¬Å"scumâ⬠in electrical appliances degrades its efficiency and will eventually reduce its life span. In addition, these can cause impairments on fabric as well, and damage water treatment plants and piping systems at a water hardness of 300 ppm CaCO3. Calcium is necessary for aquatic animals such as fish. It serves anà important role in bone formation, blood clotting, and metabolic processes of the fish and prevents the loss of important salts in the body which helps in the functioning of its vital organs such as the heart. Small amounts of calcium in water can be life-threatening to aquatic organisms like the fish. Thus, determination of water hardness is important. One method of determining water hardness is through complexometric titration. In this process, a ligand is involved in the said titration. Metal ion reacts with a particular ligand forming a complex and the equivalence point is determined by an indicator. Theà ligand used in the experiment is Ethylenediaminetetraacetic Acid (EDTA) with Eriochrome Black T indicator. EDTA is an efficient chelating agent and has an ability to bind with metal ions. Because of this, EDTA is also used in food preservation, an anti-coagulant in blood, and, when EDTA is combined with Fe(II), can even be used as an effective absorbent of harmful NO (nitric oxide). The purpose of this experiment is to determine the hardness of water through complexometric titration. METHODOLOGY Before the actual experiment, solutions of 500 mL of 0.1000 M stock EDTA solution, 250 mL of 0.0100 M standard EDTA solution, 250 mL of 0.050 M standard CaCO3 solution, 50 mL of 0.0050 M working standard CaCO3 solution, and 250 mL of 1.0 M NH3-NH4+ buffer solution were prepared quantitatively. In this experiment, the titrant used was Ethylenediaminetetraacetic Acid (EDTA), a polydentate with six bonding sites. Polydentates aid in obtaining sharper endpoints since they react more completely with cations. Likewise, reaction with polydentates only involves a single step process compared to using monodentates as titrants which involves at least two intermediate species. Among polydentates, EDTA was chosen as the titrant since it is versatile and forms most sufficiently stable chelates because of its several complexing sites which gives rise to a cage-like structure isolating the cations from solvent molecules. For the preparation of 500 mL of 0.1000 M stock EDTA solution, 18.6 g of Na2H2EDTA2H2O was weighed to the nearest 0.1 mg and was transferred into a 400 mL beaker. 200 mL of distilled waterà and 1.0 g MgCl26H2O crystals were added into the beaker and mixed until the crystals were dissolved. MgCl26H2O was added to obtain a sharper endpoint since CaIn- complex ion is less stable and endpoint will come earlier than actual. The solution was heated for faster dissolution and NaOH pellets were added to the turbid solution to produce salt EDTA making the pH of the solution higher and increasing the solubility of the EDTA. Into a 500 mL volumetric flask, the solution was transferred and was diluted to mark with distilled water. The solution was stored in a dry and clean reagent bottle. The 250 mL of 0.0100 M standard EDTA solution was prepared by getting 25 mL from 0.1000 M stock EDTA solution and diluting it to mark with distilled water in a 250 mL volumetric flask. For the preparation of 250 mL of 0.050 M standard CaCO3 solution, 1.2510 g of pure CaCO3 was weighed to the nearest 0.1mg into a 250 mL beaker and 20 mL distilled water was added. Drops of 6 M HCl were added until the CaCO3 was completely dissolved. The beaker was covered using a watch glass and was put over a hot plate. The solution was evaporated until an amount of 10 mL was left. After cooling the solution, the washings were collected by rinsing the watch glass into the beaker using distilled water. 20 mL more distilled water was added into the solution and it was transferred into a 250-mL volumetric flask. The solution was diluted to mark and was stored in a plastic polyethylene bottle since glass bottle can leach and ions from it will contaminate the solution. The 50 mL of 0.0050 M working standard CaCO3 solution was prepared by dilution of 5 mL 0.050 M standard CaCO3 into a 50-mL volumetric flask. For NH3-NH4+ buffer solution of pH 10, 2.06 g of NH4Cl was dissolved in 14.3 mL of concentrated ammonia and was diluted to mark in a 250-mL volumetric flask. Buffer solution was used since buffers are resistant to pH changes[13]. Maintaining the pH is important in preventing interference of other species during titration since different chelates form at a particular pH.[14] For the standardization of 0.01 M EDTA Solution, 10 mL each of 0.0050 M working standard CaCO3 solution was transferred into each of the three 250-mL Erlenmeyer flask using a pipette. Then, into each flask, 75 mL of distilled water was added followed by 3 mL of the NH3-NH4+ buffer solution and 2-3 drops of Eriochrome Black T (EBT) indicator. Although use of EBT indicator is unsatisfactory in calcium, it is ideal to use in magnesium titration[15], and since MgCl2 was put earlier, the number of calcium ions can be determineà using EBT indicator[16]. One at a time, the solutions were titrated with the 0.010 M standard EDTA solution. Water sample was analyzed by measuring 50 mL of commercial mineral water Viva into each of the three 250-mL Erlenmeyer flask. Then, into each flask, 75 mL of distilled water was added followed by 3 mL of the NH3 -NH4+ buffer solution and 2-3 drops of EBT indicator. One at a time, the solutions were titrated with the 0.010 M standard EDTA solution. RESULTS AND DISCUSSION Complexometric titration was used in the experiment since the reaction between the aqueous solutions of the analyte (CaCO3 solution, water sample) and titrant (EDTA) forms a complex. Which involves a coordination center composed of Ca2+ and Mg2+ and the chelating agent EDTA. EDTA, a weak acid, commonly forms 1:1 stochiometric ratio when it reacts to form soluble complexes with metal ions, this means that a single endpoint would be observed. Most of the time EDTA reacts with metals regardless of their charges. These would all correlate to a sharp endpoint in titration and a smooth calculation in stoichiometry. Titration with EDTA is affected by several factors such as the existence of complex forming ions and of organic solvents that affects the stability of the complex, the metal ion components, and the pH wherein the titration was performed. The pH range for optimal indications using EBT indicator and for better results in titration using EDTA method is from 8-10. Lower pH would form a colorless complex with EDTA while a high pH makes it hard to distinguish using the metal indicator In the experiment the pH was kept constant at 10, this was possible with the presence of the buffer solution of NH3 ââ¬âNH4Cl. It has a buffer capacity that satisfies the optimal pH range. Buffer solutions resist pH change that might be caused by other cations and the weak acid titrant, EDTA. Also, the indicator EBT would behave as it should be if there are no fluctuations in the pH. The specific pH was essential because at the pH of 10 EDTA would deprotonate just enough to bind with the metals involved. If too much buffer was added to the solution, the titration would yield defective endpoints. For example the pH was at 12, the solution would be too basic that it might form precipitates with magnesium and calcium which in turn would cause different results. The endpoint of the solution in the first trial was blue so we opt not to put KCN in the solution. KCN b onds with ironà so that iron would not affect the color change of the indicator. If iron is present in the sample it would affect the color endpoint and turn to violet instead of blue. Chemical equations that express the reaction in the titration can be shown in figure 1. Figure 1. Chemical equations involved in the titration. In the sample analysis of Viva mineral water, it contained 54mgCa/L and 14mgMg/L. After computing for the total hardness of the sample using ppm CaCO3 it was found out that the claimed total hardness was 192.6 ppm CaCO3 while the computed average ppm CaCO3 from the experiment was 139.5 ppm CaCO3this means that the calculated value from the experiment is less than the calculated total hardness of Viva mineral water according to the indicated value in the label but still in the range of hard according to the water hardness scale in table 1. Table 1 Water Hardness Scale The unit ppm CaCO3 was used because water is mostly composed of calcium and magnesium ions. Both of these ions can be expressed in terms of CaCO3 One possible source of error is the human error from differentiating color change of the indicator EBT. The solution might have turned violet but not observed making the titrant endpoint wrong because of the presence of iron. Other possible sources of error are excess buffer solution that will increase pH, calibration error of pH meter, wrong volume reading, and over titration. SUMMARY AND CONCLUSION The Complex solutions were formed by titration with the chelating agent EDTA. With the use of complexometric titration the total hardness of water sample was determined. It was found out that the water hardness of Viva mineral water is classified as ââ¬Å"hardâ⬠in terms of calcium and magnesium ions content that was expressed in terms of ppm CaCO3. The claimed total hardness of Viva Company is larger than the experimental value meaning it has less metal ion content than expected. The results of the experiment can be improved with the addition of KCN. It might not be visible that the endpoint was violetà but it would be safer to eliminate iron discrepancies in the results. REFERENCES [1] Carillo, K.J.D., Ballesteros, J.I., et al. Analytical Chemistry Laboratory Manual, 2009 edition, UP Chemistry Alumni Foundation, 2009, p. 67 [2] Skoog, D.A., West, D.M., et al., Introduction to Analytical Chemistry, 8th edition, Cengage Learning Asia Pte Ltd., 2012, p. 403 [3]Hardwater,http://water.me.vccs.edu/concepts/hardwater.html [4] Wurts, W.A., Understanding Water Hardness, http://www.ca.uky.edu/wkrec/Hardness.htm [5] Skoog, D.A., West, D.M., et al., Introduction to Analytical Chemistry, 8th edition, Cengage Learning Asia Pte Ltd., 2012, p. 372 [6] Skoog, D.A., West, D.M., et al., Introduction to Analytical Chemistry, 8th edition, Cengage Learning Asia Pte Ltd., 2012, p. 386 [7] Ethylenediaminetetraacetic acid disodium salt dehydrate,http://www.sigmaaldrich.com/etc/medialib/docs/Sigma/Product_Information_Sheet/e5134pis.Par.0001.File.tmp/e5134pis.pdf [8] Liu, N. et. al., Evaluation of Nitric Oxide Removal from Simulated Flue Gas by Fe(II)EDTA/Fe(II)citrate Mixed Absorbents, http://pubs.acs.org/doi/abs/10.1021/ef300538x?prevSearch=Uses%2Bof%2BEDTA&searchHistoryKey= [9] Skoog, D.A., West, D.M., et al., Introduction to Analytical Chemistry, 8th edition, Cengage Learning Asia Pte Ltd., 2012, p. 372 [10] Skoog, D.A., West, D.M., et al., Introduction to Analytical Chemistry, 8th edition, Cengage Learning Asia Pte Ltd., 2012, p. 384 [11] Carillo, K.J.D., Ballesteros, J.I., et al. Analytical Chemistry Laboratory Manual, 2009 edition, UP Chemistry Alumni Foundation, 2009, p. 69 [12] Ethylenediaminetetraacetic acid disodium salt dehydrate,http://www.sigmaaldrich.com/etc/medialib/docs/Sigma/Product_Information_Sheet/e5134pis.Par.0001.File.tmp/e5134pis.pdf [13] Whitten, K.[et. Al.], Chemistry.8th ed., Thomas Higher Education. USA. 2007, p. 742 [14] Skoog, D.A., West, D.M., et al., Introduction to Analytical Chemistry, 8th edition, Cengage Learning Asia Pte Ltd., 2012, p. 401 [15] Skoog, D.A., West, D.M., et al., Introduction to Analytical Chemistry, 8th edition, Cengage Learning Asia Pte Ltd., 2012, p. 399 [16] Skoog, D.A., West, D.M., et al., Introduction to Analytical Chemistry, 8th edition, Cengage Learning Asia Pte Ltd., 2012, p. 400
Home School vs. Public School Essay
I prefer home schooling over public schooling; which one do you prefer? There are both pros and cons for both Home Schooling and Public Schooling. I am going to explain this all to you in my essay. I personally was home schooled for a few years during middle and high school. All of elementary school and part of middle school I went to a regular school. My reasoning for choosing to be home schooled is I have Agoraphobia which is an anxiety disorder caused by situations where people perceive the environment as being difficult to escape or get help. As soon as I would walk into a class room I would have a panic attack. One thing I liked about public school was being able to play volleyball. I loved playing it for the little bit of time that I was in middle school. Even though I wasnââ¬â¢t really all that great, So I didnââ¬â¢t play very much. That is one con of being home schooled. You cannot play sports affiliated with any school. A pro for public schooling is you have a group environment to learn in with others to help you. On the other hand with home schooling you are on your own. In home schooling you have less choices of curriculum as you would if you were going to public school. You also have more diversity in public school. When going to public school you have a higher student to teacher ratio, now with home schooling there is a small teacher to student ratio. In home schooling you are free to choose your schedule, as in public school your schedule is strict and chosen for you. Public school chooses the curriculum for you. Unlike in home schooling you can choose your own. There are now roughly millions of children being home schooled. Being home schooled teaches students to be independent in their learning choices. Sometimes home schooling can be more expensive than going to public school. Teachers are not always qualified to teach all subjects, and colleges sometimes have stricter admission policies concerning home schooled students. It is also harder to provide social interaction when being home schooled. Like I had stated before I prefer home schooling but everyone has their own opinions. This is the reason why I have enrolled myself into the University of Phoenix online. So that I can have the flexibility of my classes, this way I can work around my everyday life and not miss out when it comes to spending time with my boys. I hope that the information in my essay was helpful to you.
Wednesday, October 9, 2019
Music Piracy Research Paper Example | Topics and Well Written Essays - 2000 words
Music Piracy - Research Paper Example The purpose is to misguide the customer that he or she is buying the original recording (Indian Music Industry, ââ¬Å"What is Piracy?â⬠par. 2). These are unsanctioned copies of music from genuine recordings for profit gain. Pirated CDs or music cassettes are named as Top Ten, Hollywood Hits or a combination of hit titles of various music companies. The pirated copy looks different than the original commercial release (Indian Music Industry, ââ¬Å"What is Piracy?â⬠par. 3). This is recording, copying, and selling of a musical performance like a live concert or broadcast without the authorization of the artist or the music company holding all copyrights of it (Indian Music Industry, ââ¬Å"What is Piracy?â⬠par. 4). End User Piracy ââ¬â It is related to duplicating of software either from one computer to another, copying office software to home computer, borrowing software to make copies for selling purpose (Indian Music Industry, ââ¬Å"What is Piracy?â⬠par. 5). Reseller Piracy ââ¬â It is deliberate reproduction with fake certificates for cheating the buyers assuming that they have purchased from the developing company (Indian Music Industry, ââ¬Å"What is Piracy?â⬠par. 6). Internet Piracy ââ¬â Peer-to-peer (P2P) downloading encourages internet piracy. Individual requests for not sharing licensed material are not adhered to. It is illegal to copy a copyrighted album on P2P service. Downloading MP3s becomes infringement when files are distributed after conversion to MP3 from CDs (Indian Music Industry, ââ¬Å"What is Piracy?â⬠par. 7). The issue of music piracy can be related to the pre-digital age of 1970s when there were legal altercations between the owners of copyrights of films and music and suppliers of technology. In one such case between Ames Records and CBS, legal action was taken by CBS for infringement on its copyrights by Ames permitting subscribers to hire records on rent. Again in 1980s CBS took legal proceedings against
Tuesday, October 8, 2019
Recruitment Quiz Essay Example | Topics and Well Written Essays - 750 words
Recruitment Quiz - Essay Example Moreover, the scientific recruitment process is usually conducted by different types of experts where time, energy and money are involved. As a result, Google and other organizations use scientific recruitment to select their employees since it has numerous advantages. In specific, Google ensures that the recruitment process goes through a thorough hiring assessment entailing recruiter screen, phone screen, and on site interview. Additionally, the Company has different experts who are used in the recruitment process such as the Hiring Committee that comprises of senior managers and directors, as well as, experienced employees who assist in making hiring decisions, thus avoiding a situation where bad decisions are made. Google also has a compensation committee that is concerned with ensuring that appropriate decisions are made in relation to what should be given to the qualified employees in terms of compensation for the offer. In a general sense, the scientific recruitment at Google has ensured that there is the right job for the right person, and high efficiency and productivity for the organization advantage (Kumar 2 62). 1. Identifying the gap: the HR department begins by identifying the gaps that are present in different department within the Company, which are as a result of employee turnover and/or increased amount of work that requires extra sources of labor. 2. Advertisement: the HR manager then consult the senior manager who is expected to give an approval on the necessity of recruiting more employees, and further give directions to the advertising department in reference placing the job adverts on various platforms that can easily be accessed by potential job seekers. 3. Screening: The recruiter goes through the applications sent in and matches them with the qualifications and experiences that are required by the Company. The rot that has all or most qualifications depending
Monday, October 7, 2019
Ecology paper Essay Example | Topics and Well Written Essays - 250 words
Ecology paper - Essay Example The focus of study in the article was to understand how invasive species, pathogens and disease vector affect human health and determine appropriate measures to reduce disease emergence. The study depicts that invasive species and infectious diseases have become prevalent and widespread because of the increased connectivity in human population. The connectivity in the current world has attributed to the disease outbreak. The new developed trade routes in the previously disconnected countries increase human interactions. Crowl et al., (2008) demonstrated that the enhanced transport systems such as airplanes have increased spread of pathogens. The invasive species has become the second contributing aspect to extinction and endangerment of species in the United States after the increased human population and related activities. The United States government spends almost 120 billion dollars to cater for the non-native species in the country (Crowl et al., 2008). The evidence used to support contrasting point of view was the explanation of the spread of the avian-dispersed H5N1 avian influenza disease worldwide. In-depth and integrated network of research platform was es sential in full understanding of the spread and impacts of the invasion species. The point of view that I most agreed with was the fact that modern technology such as airplanes contributes to the increasing spread of pathogens and invasive species. Most disease in the world emerges from a single area and spread to the entire world. The point became convincing because of the evidence given involving the spread of avian-dispersed H5N1 avian influenza disease. Other points of view in the article such as cause of non-native species extinction became less convincing because of lack of material evidence. Crowl, T. A., Crist T.O, Parmenter, R. R., Belovsky, G., & Lugo, A. E. (2008). The spread of invasive species and infectious disease as drivers of ecosystem change.
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